The ‘2025 Korean Chemistry Olympiad Winter School,’ hosted by the Department of Chemistry at UNIST, concluded successfully, fostering a new generation of talented young chemists. About 52 first- and second-year high school stude... Read More
Professor Jaeheung Cho in the Department of Chemistry at UNIST has been honored with the James Hoeschele AsBIC Award at the 2024 Asian Biological Inorganic Chemistry (AsBIC) Conference, held on December 5, 2024. With this prestigious award,... Read More
Abstract The intrinsic relationship between spin states and reactivity in peroxocobalt(III) complexes was investigated, specifically focusing on the influence of steric modulation on supporting ligands. Together with the previously reported... Read More
Abstract A series of mononuclear manganese(III)–hydroxo and −aqua complexes, [MnIII(TBDAP)(OH)2]+ (1), [MnIII(TBDAP)(OH)(OH2)]2+ (2) and [MnIII(TBDAP)(OH2)2]3+ (3), were prepared from a manganese(II) precursor and confirmed using various me... Read More
Abstract Oxidation of unactivated alkanes, which requires substantial energy for conversion to valuable organic chemicals, is a major challenge in both industry and academia. Herein, we describe how solvents affect and improve the catalytic... Read More
Abstract Recently, transition-metal terminal nonoxo complexes have shown a remarkable ability to activate and functionalize C–H bonds via proton-coupled electron transfer (PCET). Here we report the first example of a mononuclear manganese(I... Read More
Abstract The versatile applications of nitrile have led to the widespread use of nitrile activation in the synthesis of pharmacologically and industrially valuable compounds. We reported the activation of nitriles using mononuclear cobalt(I... Read More
Abstract Retinal vascular occlusion (RVO) is a common cause of visual impairment. Although several approaches, including vasodilators, have been explored to treat retinal vascular occlusion, there is no proper method to treat this obstructi... Read More
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